The change I-vi (C-Am) is pretty rare, I-V (C-G) leads the polls in two-chord songs. As said, Fsus2 (0010) combined with C7 (0001) is the easiest entry into chord changing, and you have a more universal I-V change with just one finger there. As for Am-C, only 'Psycho Killer' by the Talking Heads comes to my mind, although the chorus also passes by an F and a G chord and the bridge even pushes it to a Bm.
Why not stick to single chord? A lot of groove based music doesn't change chords, so look at blues and reggae. It does require the lyrics or rhythm to become more interesting, or else it will sound like practice.
- 'All around the kitchen' by Dan Zanes is basically an Am, but you can throw in a C to make it more interesting. You can play along with the youtube video this way.
- You can play Bob Marley's 'Get Up Stand Up' with the same single Am chord (the original is a Cm, that's not too far off, but the transposition means you can't jam along with Bob).
- Some say 'Papa was a Rolling Stone' is just an Em, but is actually switches back and forth to an Am (you could transpose that to Am and Dm, if you wish). I would start out by teaching an Em7 (0202) and call that the 'finger bridge'. When you're teaching, just start that song in Am and shout 'take me to the bridge!'
- Exactly the same for 'A Horse with no Name'
If you can add an F (I know, that requires two fingers already), the possibilities open up - if you're teaching a teenager, Avincii's 'Wake me up' comes to mind: Am-F-C-C throughout. The original is two steps higher, though, although Aloe Blacc does change keys when doing acoustic versions. You can even play or teach the song the abovementioned Fsus2 replacing the F, using three one-finger chords: 2000, 0010, 0003. Ideally, those use three different fingers: middle finger, index and ring finger.